A research group from RIKEN and Kyushu University has developed a new type of material, based on ethylene, which exhibits a number of useful properties such as self-healing and shape memory. Remarkably, some of the materials can spontaneously self-heal even in water or acidic and alkali solutions. The new material is based on ethylene, a compound that is the source of much of the plastic in use today.
Materials that can self-heal have become a popular area of research during the last decade, and a variety of materials have been developed. However, most of the self-healing materials reported to date have relied on sophisticated designs that incorporate chemical mechanisms into polymer networks, such as irreversible or reversible covalent-bond formation, hydrogen bonding, metal-ligand interactions, or ionic interactions. As a result, they require some external stimulus, such as heat or pressure, to prompt them to heal, and in most cases, they do not function in water, acid or alkaline solutions because the chemical networks cannot survive such conditions. The ideal is to create a material that possesses sufficient toughness and can autonomously self-heal under various conditions.
For the present research, published in the Journal of the American Chemical Society, the researchers used a catalyst based on scandium, a rare metal, to create polymers composed of alternating sequences of ethylene and anisylpropylenes and shorter ethylene-ethylene segments by the copolymerization of ethylene and anisylpropylenes. This new class of well-defined, functionalized polyolefins ranged from soft viscoelastic materials—materials that can be both elastic but also exhibit liquid-like properties—to tough elastomers, which can be stretched but return to their original shapes, and rigid plastics. The elastomer copolymers were very elastic, and tough, and also showed remarkable self-healing property, as they autonomously self-healed when subjected to mechanical damage not only in a dry environment but also in water and aqueous acid and alkaline solutions, without the need for any external energy or stimulus.
According to Zhaomin Hou of the RIKEN Center for Sustainable Resource Science and the RIKEN Cluster for Pioneering Research, who led the research team, “We had learned from our previous work that a scandium catalyst would be a useful way to create the copolymers of ethylene and anisylpropylenes, but we were astounded by the special properties that this class of materials exhibited. We look forward to working to find applications for these different films, which can be made easily from ethylene and other olefins.”
Haobing Wang et al. Synthesis of Self-Healing Polymers by Scandium-Catalyzed Copolymerization of Ethylene and Anisylpropylenes. Journal of the American Chemical Society (2019). DOI: 10.1021/jacs.8b13316
Top panel: Optical microscope images of damaged (left) and repaired (right) samples of one of the materials in air at 25 °C. A film was cracked by razor blade and then left in air for 5 minutes for healing. Bottom panel: Optical microscope images of damaged (left) and repaired (right) samples of one of the films in water at 25 °C. The film was cracked by a razor blade and then left in water for 5 minutes for healing.