A technique to stabilise alkali metal vapour density using gold nanoparticles, so electrons can be accessed for applications including quantum computing, atom cooling and precision measurements, has been patented by scientists at the University of Bath.

Alkali metal vapours, including lithium, sodium, potassium, rubidium and caesium, allow scientists to access individual electrons, due to the presence of a single electron in the outer ‘shell’ of alkali metals.

This has great potential for a range of applications, including logic operations, storage and sensing in quantum computing, as well as in ultra-precise time measurements with atomic clocks, or in medical diagnostics including cardiograms and encephalograms.

However, a serious technical obstacle has been reliably controlling the pressure of the vapour within an enclosed space, for instance the tube of an optical fibre. The vapour needs to be prevented from sticking to the sides in order to retain its quantum properties, but existing methods to do this, including directly heating vapour containers are slow, costly, and impractical at scale.

Scientists from the University of Bath, working with a colleague at the Bulgarian Academy of Sciences, have devised an ingenious method of controlling the vapour by coating the interior of containers with nanoscopic gold particles 300,000 times smaller than a pinhead.

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When illuminated with green laser light the nanoparticles rapidly absorb and convert the light into heat, warming the vapour and causing it to disperse into the container more than 1,000 times quicker than with other methods. The process is highly reproducible and, in addition, the new nanoparticle coating was found to preserve the quantum states of alkali metal atoms that bounce from it.

The study is published in Nature Communications.

Professor Ventsislav Valev, from the University of Bath’s Department of Physics led the research. He said: “We are very excited by this discovery because it has so many applications in current and future technologies! It would be useful in atomic cooling, in atomic clocks, in magnetometry and in ultra-high-resolution spectroscopy.”

“Our coating allows fast and reproducible external control of the vapour density and related optical depth, crucial for quantum optics in these confined geometries.”

Assoc. Prof Dimitar Slavov, from the Institute of Electronics in the Bulgarian Academy of Sciences, added “In this proof of principle, it was demonstrated that illuminating our coating significantly outperforms conventional methods and is compatible with standard polymer coatings used to preserve quantum states of single atoms and coherent ensembles.”

Dr. Kristina Rusimova, a prize fellow in the Department of Physics, added: “Further improvements of our coating are possible by tuning particle size, material composition and polymer environment. The coating can find applications in various containers, including optical cells, magneto-optical traps, micro cells, capillaries and hollow-core optical fibres.”


Provided by: University of Bath

More information: Kristina R. Rusimova et al. Atomic dispensers for thermoplasmonic control of alkali vapor pressure in quantum optical applications. Nature Communications (2019). DOI: 10.1038/s41467-019-10158-4

Image: Gold nanoparticles rapidly absorb green laser light and convert it into heat, warming vapour in the tube.
Credit: Prof Ventsislav Valev