Lead researcher UC Civil Engineering Associate Professor Allan Scott, and his team in the United States, United Kingdom and New Zealand, have found a new low-carbon method to produce the common mineral, magnesium hydroxide or Mg(OH)2.
Associate Professor Scott explains magnesium hydroxide has been widely recognized as one of the most promising materials for ‘carbon mineralization’ (where carbon dioxide or CO2 is prevented from entering the atmosphere), but until now there hasn’t been an energy-efficient way of producing it.
“Most processes to get magnesium hydroxide typically involve CO2 emissions. We are proposing a new method to produce magnesium hydroxide from olivine; an abundant mineral here in New Zealand and around the world. Our method uses existing technology, produces useful by-products and most importantly there’s low to zero CO2 emitted during the process.”
In the new paper published in Communications Earth & Environment, the researchers outline that olivine can be ground into powder, combined with hydrochloric acid and a process of electrolysis can be used to produce magnesium hydroxide. Lab trials showed that 100 tons of olivine could potentially produce 35 tons of magnesium hydroxide, as well as 35 tons of amorphous silicate—a material used in products such as semiconductor circuits and cement.
“The discovery of this method has the potential to have a dramatic impact on our ability to reduce global CO2 emissions,” Associate Professor Scott says.
Around 40 billion tons of human-made CO2 is released into the atmosphere each year that contributes to global warming. Of that, ‘point source’ emissions such as power generation [coal plants, natural gas] and industrial production account for roughly 50 percent of the total CO2.
“This new method makes it possible to produce magnesium hydroxide on a large scale, which can then be transported to industrial and manufacturing sites to mineralize the CO2 produced,” he says.
“In theory it’s possible to remove and sequester at least half of the 40 billion tons of CO2 and continue to do so for thousands of years. The challenge now is how we take this method from the lab to an industrial-scale process which can be widely distributed at a reasonable cost.”
The research team led by Associate Professor Allan Scott, includes Occidental College and former UC academic Christopher Oze, UC Postdoctoral Researcher Vineet Shah, UC Ph.D. student Nan Yang, UC Associate Professor Aaron Marshall and UC Associate Professor Matthew Watson, Imperial College London Professor Chris Cheeseman and Barney Shanks.
What is Mg(OH)2?
Magnesium hydroxide Mg(OH)2 is a highly reactive material that when combined with carbon dioxide (CO2) – one of Earth’s most significant greenhouse gases—produces magnesium carbonates, an inorganic salt which is used in a variety of commercial products such as flooring, fireproofing and bricks.
Provided by: University of Canterbury
More information: Allan Scott et al. Transformation of abundant magnesium silicate minerals for enhanced CO2 sequestration. Communications Earth & Environment (2021). DOI: 10.1038/s43247-021-00099-6
Image: Associate Professor Allan Scott is leading a team of international researchers who have discovered a new method of producing magnesium hydroxide, which they believe is key to reducing greenhouse gas emissions.
Credit: University of Canterbury