Graphene is actually a 3-D material as well as a 2-D material, according to a new study from Queen Mary University of London.
Realising that it is a 3-D material is important for understanding its mechanical properties and for developing novel graphene-based devices.
Often hailed as a ‘wonder material’, graphene has the highest known thermal and electrical conductivity, is stronger than steel, light, flexible and transparent. Its uses are wide-ranging and recently it has been shown it could even act as a barrier against mosquito bites.
In this study, published in the journal Physical Review Letters, the researchers asked two fundamental questions: to what extent is graphene graphite, and what is the true thickness of graphene?
To their surprise, they found that 2-D graphene, which is a flat single layer of carbon atoms arranged in a honeycomb structure, has many of the same mechanical properties as 3-D graphite, which is a naturally occurring form of carbon made up from a very weak stack of many layers of graphene.
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They show that graphene shares a similar resistance to compression as graphite and that it is significantly thicker than is widely believed.
If the thickness of a block of graphite 100 layers thick is measured, the thickness of a single graphene layer is simply the thickness of the graphene block divided by 100. Therefore, it is reasonable to consider the thickness of graphene as 0.34 nm.
Dr. Yiwei Sun, lead author of the study from Queen Mary University of London, said: “Graphene owes its thickness to an array of chemical bonds sticking out above and below the 2-D plane of carbon atoms. Hence graphene is really a 3-D material, albeit with a very small thickness.
“By applying conventional 3-D theory, which has been used for around 400 years, to 2-D materials such as graphene, which have been known for 15 years, we show that similar arguments apply to other so-called 2-D materials, such as boron nitride and molybdenum disulphide. In that sense, 2-D materials are actually all 3-D.”
Graphene is often called the world’s first two-dimensional material. It was discovered in 2004 by peeling off graphene flakes from bulk graphite (used in pencil leads and lubricants) using sticky tape.
It is regarded as part of a new class of 2-D materials and it is currently modelled by scientists as a sheet of atoms with very little depth, hence the name 2-D material.
More information: Y. W. Sun et al. 3D strain in 2D materials: to what extent is monolayer graphene graphite? Physical Review Letters (2019). https://journals.aps.org/prl/accepted/4b077Yf9Q051846ab8ea22a839e77eeea913dbf09
Image: The Queen Mary research shows that graphene is 3D as well as 2D.
Credit: Yiwei Sun